Product ID:SMOKE TUBES, S-31
MSDS Date:04/06/1989
FSC:6850
NIIN:00N021724
MSDS Number: BLNVL

Emergency Phone: 203-222-3000

Info Phone: 203-222-3000

Cage: 8F901

Telephone: 203-925-3300/CHEMTREC 800-424-9300

Cage: 8F901

TITANIUM TETRACHLORIDE (SARA III)

CAS: 7550-45-0

RTECS: XR1925000

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INGEST:MAY CAUSE IMMED IRRIT OF MOUTH/
THROAT/GI TRACT WHICH MATL CNTCTS. NAUS/VOMIT/CRAMPS/DIARR MAY
FOLLOW. IN SEV CASES, TISS ULCERATION & CNS DEPRESS. EYE:LIQ/VAPS
ARE CORR. CONJUNCT & CORNEAL DMG MAY RESULT IF MATL IS NOT QUICKLY
WASHED AWAY BY THORO IRRIGATION W/H2O. SKIN:THERMAL & ACID BURNS
MAY(EFTS OF OVEREXP
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:RESULT FROM CNTCT W/MOISTURE.
INHAL:MAY PRODCE SEV IRRIT TO UPPER RESP TRACT W/COUGHING, BURNING
OF THROAT/HDCH/DIZZ/WEAK. LUNG DMG & PULM EDEMA MAY OCCUR AFT SEV
EXPOS. BRONCH IRRIT W/CHRONI C COUGH & BRONCH PNEUM MAY RESULT FROM
PRLNG/RPTD EXPOS TO LOW CONC.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:REMOVE FROM CONTAM ATMOSPHERE. IF DISCOMFORT PERSISTS,
SEE MD. EYES:IMMED FLUSH W/RUNNING WATER FOR @ LST 15 MIN. HOLD
EYELIDS APART. DO NOT ATTEMPT TO NEUT W/CHEM AGENT. OILS/ OINTMENTS
SHOULD NOT BE USED UNLESS DIRECTED BY MD. SKIN:IMMED FLUSH
AFFECTED AREA W/WATER. DO NOT ATTEMPT TO NEUT W/CHEM AGENTS. CALL
MD. INGEST:GIVE LG AMTS OF WATER OR WARM SALTY WATER TO INDUCE
VOMIT. CALL MD.

Extinguishing Media:NONFLAMMABLE IN ITSELF. DRY POWDER OR CO2 MAY BE
USED.
Fire Fighting Procedures:H2O IS NOT TO BE USED IN FIRE WHERE H2O CAN
CNTCT TITANIUM TETRACHLORIDE. H2O MAY BE SPRAYED ON OUTSIDE OF
CNTNRS TO KEEP THEM COOL. USE NIOSH/MSHA (SUPDAT)
Unusual Fire/Explosion Hazard:REACTS W/WATER TO RELEASE HYDROGEN
CHLORIDE. THIS REACTION WILL GENERATE CONSIDERABLE AMOUNT OF HEAT.

Spill Release Procedures:IN SM SPILLS:SPREAD SODIUM CARBONATE SODIUM
BICARBONATE OVER TITANIUM TETRACHLORE TO PREVENT ESCAPE OF HYDROGEN
CHLORIDE & DRY MASS CAN BE SWEPT OR FLUSHED AWAY W/WATER WITHOUT
FUMES. LG SPILLS:DRENCH AREA W/COPIOUS QTYS OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AWAY FROM WATER OR MOISTURE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATORS APPROVED FOR
USE WITH TITANIUM TETRACHLORIDE.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Protective Gloves:RUBBER GLOVES.
Eye Protection:CHEMICAL WORKER GOGGLES .
Other Protective Equipment:PROTECTIVE CLOTHING. EMERGENCY EYEWASH &
DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . MATLS TO
AVOID:TO OXYCHLORIDE OR OXIDE W/ FORMATION OF HYDROGEN CHLORIDE
WHICH IS CORROSIVE TO MOST METALS INCLUDING CARBON STEEL.

HCC:T3
Boiling Pt:B.P. Text:277F,136C
Vapor Density:14.68
Spec Gravity:1.726
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

Stability Indicator/Materials to Avoid:YES
UNDER COMPLETELY ANHYDROUS CNDTNS, MILD CARBON STEEL MAY BE USED,
HOWEVER, ANY MOISTURE WILL CAUSE HYDROLYSIS (SUPDAT)
Stability Condition to Avoid:KEEP FREE OF MOISTURE.
Hazardous Decomposition Products:UNAVAILABLE.

Waste Disposal Methods:CONTACT STAUFFER CHEMCIAL CO FOR RECOMMENDATIONS
ON DISPOSAL OF UNUSED MATERIALS. DISPOSAL MUST BE I/A/W FEDERAL,
STATE & LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.